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Burning ethanol has the effect of increasing octane, not decreasing it. If anything, the Sunoco 94 with 20% ethanol is probably 91 octane gas, and the ethanol raises the overall octane to 94.
Also, are you sure there is a 20% ethanol content? I don't think non E85 cars are rated to run on anything about 10%. (at least in the US, I'm not sure if things are different in Canada). If it were my car, I'd use gas with no ethanol anytime I can find it. A 20% blend may effect your warranty.
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