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It probably is rust... surface rust. Its harmless and can appear overnight. Nothing you can do to prevent it because the rotor surfaces are bare metal.
Drive it around the block and it'll be gone.
BTW, try to avoid getting detailer (or any chemicals) on your brakes as they can act like a lube and increase braking effectiveness.
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Black 2SS ordered 1/4/2010, received 2/19/2010
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