like some of the others said, decide what will work better for you as far as driving around family/friends or just you and someone else riding in it. what options are you getting with both for 33k. for that price you should be completely maxed for the v6 Camaro. The r/t charger for that price has a lot of options included with it so decide which opts you can't live without. if opts are a deciding factor, you could get a near base v6 Camaro, for around 23k and use the 10k saved to personalize it. I'm sure you can get a lot more power out of it also with money to spare.
if only I thought of this when I was looking to buy my Camaro a few years ago. v8 vs. v6 you can't duplicate that v8 sound. go with the v6 you'll have the looks and whatever else pros come with it. go with the r/t and you'll have the pros that come with it (power, tq, sound, etc.). We can tell you which one we would chose but it still won't change your reasoning for why YOU want it. knowing what I know now and my experience with owning a v6, I would say v8, but you won't have those dashing great looks of the Camaro unless you get one. maybe v8 Camaro??
